Polish National Programme on safe CO2 geological storage

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Polish National Programme on safe CO2 geological storage Adam Wójcicki, PGI-NRI

CO2 geological sequestration (CCS)

CO2 storage projects - Poland 1995-..Borzęcin gas field (acidic gas 60% CO2) 2004-2008 Kaniów coal beds (RECOPOL& MoVeCBM) Bełchatów demo CCS project (EEPR) Kędzierzyn demo CCS project planned Regional studies

Estimations of CO2 storage capacity (PL) Type CASTOR EU GeoCapacity CO2 Atlas of Poland Cr1, J1, T formations (upper limits) Storage potential, Mt 3 752 3 522 8 299 ~90 000 Hydrocarbon fields (31 structures) 764 Coal seams (selected CBM fields at depth of 1-2 km) Coal seams within Polish SCB at depth of 1-2 km SUM SUM 414 1 254 5-9.5 Gt ~92 Gt Saline (Mezozoic) aquifers are of biggest potential and sufficient to store emissions of big plants, Hydrocarbon fields (mostly gas) are of small capacity, Coal seams (methane recovery) are of local importance (SCB), the technology is not mature yet.

Perspective sedimentary basins EU GeoCapacity project mapped perspective sedimentary basins of Europe, (southern) Permian- Mezozoic basin is the biggest one, It covers a large portion of Poland, so the country (onshore) CO2 storage potential is above the average.

The Polish basin aquifers (z= 1km; Kotański, 1997) Lower Jurassic Triassic Lower Cretace ous

Legal issues The Directive on CO2 geological storage is being implemented in Poland; The assumptions on relevant amendments of geological and mining law, environmental, economic law, etc., accepted by the Council of Ministers, after a long process of consultations with public and government agendas; Now research CO2 injection up to 100 kt per well allowed; CO2 storage of over 100 kt will be governed by the geological and mining law (same as, for example, hydrocarbon production) where Ministry of Environment is the authority; Storage fee of 1.25 /t CO2 injected 60% goes to the commune/municipality where injection is located.

Qualification of CO2 storage potential Zatłaczanie Składowisko Matched or Viable Capacity Pojemność realistyczna Realistic Capacity 4 - wykonalność (opłacalność) składowania; viable storage 3 - bezpieczne składowanie safe storage 2 - nie ma konfliktów interesów no competing interests Większa wiarygodność Większe nakłady Spadek pojemności do wykorzystania Pojemność teoretyczna Theoretical Capacity 1 - mniejsze obszary albo struktury geologiczne spełniające kryteria wyjsciowe; smaller areas or structures of geological cut-off limits 0 - oszacowania w skali basenów (objetość przestrzeni porowych); basin wide estimates based on pore space volumes CO2 storage capacity pyramid for the key option - saline aquifers (based on Bachu, 2003 and others)

The Programme Assessment of formations and structures for safe CO2 geological storage including monitoring plans ; Ordered by Ministry of Environment (=the permiting authority of Directive on geological storage of CO2). Conducted by 6 national institutions (PGI-NRI leader, AGH-UST, CMI, MEERI, O&GI, PBG). Timeframe: 10.2008-09.2012; ~80 persons involved; Goals: Supporting Polish demo projects, Providing the permitting authority with information necessary for implementing CO2 storage, Cooperation with other stakeholders, R&D organizations.

The scope of the programme (geology) MOŻLIWOŚCI GEOLOGICZNEJ SEKWESTRACJI CO2 W POLSCE POSSIBILITIES ON CO2 GEOLOGICAL SEQUESTRATION IN POLAND VIII KAUNAS KALININGRAD Gdynia ALYTUS GDANSK Gdansk Koszalin Elblag Suwalki Tczew VII Neubrandenburg Elk OLSZTYN SZCZECIN HRODNA Grudziadz Stargard_Szczecinski Pila Lomza BYDGOSZCZ BIALYSTOK Ostroleka TORUN GORZOW_wLKP. Inowroclaw BERLIN Wloclawek Plock Gniezno Frankfurt(Oder) VI ZIELONA_GORA Cottbus III Konin Siedlce BREST Zgierz Kalisz LODZ Ostrow_Wielkopolski Pabianice I Lubin Legnica Görlitz Legionowo WARSZAWA Pruszkow Biala_Podlaska Leszno Glogów DRESDEN Plock POZNAN Tomaszow_Mazowiecki Radom Piotrkow_Trybunalski Belchatow WROCLAW V Kovel LUBLIN Chelm Starachowice Jelenia_Gora Decín USTI_NAD_LABEM Teplice Victoria Ostrowiec_Swietokrzyski Swidnica Walbrzych KIELCE Czestochowa Czestochowa Novovolynsk Zamosc OPOLE Most Tarnobrzeg Stalowa_Wola II Zawiercie Tarnowskie_Gory Zdzieszowice Kladno Chervonograd Piekary_Slaskie Bytom Bytom Kedzierzyn-Kozle Przyjazn Dabrowa_Gornicza JadwigaZabrze Bedzin Siemianowice_Sląskie GliwiceSwietochlowice Chorzow Sosnowiec Ruda_Slaska HRADEC_KRALOVE KATOWICE Myslowice Jaworzno PRAHA Debiensko Trzebinia_EC Tychy Raciborz Rybnik Radlin Zory PARDUBICE Krakow KRAKOW Jastrzebie-Zdroj Opava IV Mielec RZESZOW Tarnow LVIV Czechowice-Dziedzice Miasta, tys. Cities, thous. 0 25,000 50 to 99 100 to 249 250 to 999 1000 to 3500 50,000 75,000 100,000 125,000 150,000 175,000 200,000 KM OLOMOUC Karvina OSTRAVA Havirov Przemysl Bielsko-Biala Frydek-Mistek Nowy_Sacz JIHLAVA Drogobych Stryj BRNO ZLIN ZILINA CESKE_BUDEJOVICE Martin Kalush Poprad PRESOV Obszary chronione (NATURA 2000, parki narodowe) Protected areas (NATURA 2000, national parks) LEGENDA LEGEND Elektrownie zawodowe, emisja w kt (KPAU) Power plants, emission in kt 100 to 1000 1000 to 5000 5000 to 10000 Elektrociepłownie i ciepłownie, emisja w kt (KPAU) CHP and heating plants, emission in kt 100 to 1000 1000 to 5000 10000 to 33000 Rafinerie i koksownie, emisja w kt (KPAU) Conversion plants emission in kt 100 to 1000 1000 to 6000 Przemysł wytwórczy, emisja w kt (KPAU) Manufacturing industries, emission in kt 100 to 1000 TRENCIN Prievidza Zasięg dolnego triasu (pstrego piaskowca) Lower Triassic (Bunter Ss.) extent (R. Dadlez, S. Marek, J. Pokorski, 1998) Planowane lokalizacje geotermalne Planned geothermal localities Instalacje i uzdrowiska geotermalne Geothermal installations and spas Potencjal magazynowania struktur hydrogeologicznych (Cr1, J1, T1), Mt Storage capacity of aquifer structures (Cr1, J1, T1 - R. Tarkowski, 2005), Mt 100 to 500 1000 to 5000 5000 to 10000 BANSKA_BYSTRICA Zasięg dolnej kredy (W. Górecki, 1995) Lower Cretaceous extent Zasięg dolnej jury (W. Górecki, 1995) Lower Jurassic extent Gazociągi (P. Karnkowski, 1993; www.rynekgazu.pl) Gas pipelines Terminale gazowe (st. kompresorów, przesyłowe) Gas pipelines (compressor & transfer stations) Ropociąg "Przyjaźń" Druzhba oil pipeline Ważniejsze podziemne magazyny gazu i paliw Major underground gas and fuel storages Wybrane zloża gazu i ropy (P. Karnkowski, 1993; Infogeoskarb) Selected gas and oil fields Potencjal magazynowania struktur naftowych (gaz i ropa), Mt Storage capacity of hydrocarbon structures, Mt 0.4 to 5 5 to 10 10 to 50 500 to 1100 50 to 150 Obszary górnicze (w tym MPW) Mining areas (including CBM Infogeoskarb) GZW (zasięg karbonu produktywnego) Silesian Coal Basin (Carboniferous range) Eksperyment Recopol/MoveCBM (ECBM) ECBM Recopol/MoveCBM experiment Zasoby MPW CBM fields (S. Przeniosło, 2005) 2 to 10 10 to 25 25 to 50 Zasięg Zapadliska Przedkarpackiego Carpathian Foredeep extent (P. Karnkowski, 1993) Front nasunięcia Karpat Carpathian front (P. Karnkowski, 1993) Zasięg czerwonego spągowca Rotliegend range (P. Karnkowski, 1993) It covers entire territory of Poland and the Baltic economic zone, but is focused on*: regional studies for 8 areas with saline aquifers, hydrocarbon fields and coal beds in general, case studies for saline aquifer structures (4), case studies for hydrocarbon fields (2) and coal beds (1). reinterpretation of archive data, laboratory analyzes Naturalne ekshalacje CO2 Natural CO2 seeps 13-14 April 2011 1st Awareness raising Workshop - Vilnius

The regional studies The following geological formations are perspective for the regional study areas of saline aquifers: I (central) Jurassic (J1, J2 sandstones); II (S) Miocene; III (central-ne) - Jurassic (J1, J2 sandstones), T, Cr1; IV (SE) Carpathian front foredeep (Cr to Cm); V (E) Carboniferous (C3 sandstones), J, Cm; VI (W) Permian (P1), T, J; VII (NW) Jurassic (J1 sandstones), T3, T1 a small part offshore; VIII (N, incl. offshore area E part of Polish Baltic economic zone) Cm2, T.

The progress of the programme (~12-14 Gt) Case studies in saline, aquifers, hydrocarbon fields and coal beds. J&T Cm2 Central, S, SE and E parts of the country screened and assessed in depth, W and NW area in progress, N area (incl. a large area offshore) left for 2012. Hydrocarbon fields and coal beds in general, assessed.

Site screening/selection criteria (based on CO2STORE guidelines) Seal thickness: minimum 50 m, seal integrity is essential Aquifer depth: from 800 m to 2500+ m Aquifer net thickness: minimum 20-30 m (~a single layer) Porosity of the reservoir: minimum 10%, preferably 20% Permeability of the reservoir: minimum 50-100 md Salinity: minimum 30 g/l, in case of relic, isolated fluids it might be lower Capillary entry pressure is the caprock good enough, impermeable (if K<0.0005-0.005 md it is likely safe)? Information necessary to evaluate the structure against criteria mentioned above

Works for area I - 1st Polish demo project (Bełchatów, 1.8 Mt/yr) B-Z structure was selected (of sufficient data coverage, though not ideal) and two backup sites/areas were proposed to the investor (PGE).

Well correlation and aquifer mapping J1 caprock and aquifer formations within the supercritical range

Well data analyzes (6 wells within B-Z structure)

2-D seismic for the site (17 old lines, 3 newer)

The site model and proposed surveys (site characterization and baseline monitoring) Static capacity (J1) 370 Mt (Bełchatów needs 45 Mt; Kędzierzyn 35 Mt)

Injection simulations (AGH-UST) of J1 (0, 5, 20 y. of injection; 25 y. after; storage capacity 100-500 Mt) CO2 na plume area ~14 x 14 km (max.)

Field works of PGE Bełchatów (the backup structures; not a part of the programme) Field works The backup sites were explored (2D seismic, 2 wells) and models are being constructed, In NE there is nature protected area longer approval procedures, In SW public opposition encountered (an NGO), a few lines relocated. 1st Awareness raising Workshop - Vilnius

Pilot injection project (another initiative; not a part of the programme) An initiative of Ministry of Environment, funded by an association of Polish power plants. Location in central Poland, not far from the demo site(s) J1 (Jpl) aquifer as for demo site(s) Duration 3 years One injection well, one observation well (~1400 m) Reservoir properties effective porosity likely 20%; permeability 200-500 md; temperature 45 C; pressure ~12.5 MPa Goal to evaluate injectivity of J1 aquifer Amount of CO2 injected 27 kt within 2 years Project status contract ready for signing, land being purchased, geological study evaluated by experts of Ministry of Environment Project starts within several weeks

Pilot injection project profile and design of the wells 1st Awareness raising Workshop - Vilnius

Pilot injection project injection simulations (AGH-UST) the CO2 plume range practically stabilizes after two year injection stops (~200 m radius) 1st Awareness raising Workshop - Vilnius

Works for area II 2nd Polish demo project (Kędzierzyn, 1.4 Mt/yr; PGI US & CMI) Kędzierzyn Principal aquifer dębowieckie beds of Lower Miocene + basement (zamarskie beds, Upper Carboniferous), Insufficient storage capacity 25 Mt after injection simulations (at least 35 Mt required), Other options considered gas fields NW of Wrocław and saline aquifers in central Poland (200 km distance). 1st Awareness raising Workshop - Vilnius

Hydrocarbon fields (Nosówka oil field in SE Poland; O&GI/INiG) Reservoir C1 (Visean) Caprock Lower Miocene OOiP 4.5 mln t; OGiP 0.585 bln m3 UR of oil 0.9 mln t, gas 0.117 bln m3 1st Awareness raising Workshop - Vilnius

Hydrocarbon fields (Wilków gas field in W Poland; AGH-UST) Reservoir P1 (Rotliegend) Caprock Zechstein OGiP 5.5 bln m3; UR 4.4 bln m3 Storage capacity 14-20 Mt 1st Awareness raising Workshop - Vilnius

Conclusions Ongoing research of the National Programme and previous projects provide the following conclusions: CO2 storage capacity of Poland is sufficient (equals 50-70 years of emissions listed in ETS); The most of storage potential is located onshore (>90%), offshore mostly in E Baltic area; The best aquifers are of Mezozoic formations (especially J1, to lesser extent T3&T1; Cr3 is not always safe) Case study of B-Z structure (the 1st Polish CCS demo) provided promising results and such structures are a quite numerous J1 injectivity shall be proven by a field experiment Miocene aquifers are not so good, as well as (likely) C1. Hydrocarbon fields and coal beds are of limited storage capacity, same in case of EHR potential.

Thank you for your attention: www.pgi.gov.pl