Report summarizing work in the period from 1 April 2013 to 30 June 2013. WP 6.2a. Support of the analytical potential by the purchase of SEM



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Warsaw, 16th July 2013 Report summarizing work in the period from 1 April 2013 to 30 June 2013 WP 6.1. Recruitment of the Project Manager Completed WP 6.2a. Support of the analytical potential by the purchase of SEM 1. Advanced course Three of the operators of the SEM microscope were delegated to the Eindhoven (Holland) to participate in an advanced course in which different techniques of SEM measurements were addressed. The course took place between 10 and 12 June 2013 in the headquarters of the FEI company, producer of the microscope purchased by the Institute of Physical Chemistry. The following persons were delegated: Dr Witold Adamkiewicz Dr Marcin Hołdyński Dr Martin Jonson-Niedziółka The course has been conducted by Dr Adrian Sandu, an experienced professional employed in the FEI company. The following issues were addressed: - Application of specific techniques for collecting images for different materials - Demonstration of operation of detectors for backscattered electrons. - Work with samples that require measurements in low vacuum (use of detectors Helix, LVD and GAD) - Demonstration of scanning transmission microscopy (STEM) Detailed training report is attached hereto. 2. Basic courses In the Institute of Physical Chemistry, a number of employees took interest in application of SEM in their research. Over forty persons are willing to participate in a basic course that would make possible the use of SEM in typical measurements.

It has been decided that four operators which participated in advanced courses can conduct the basic course for interested colleagues. Four operators were selected to lead the basic courses: Dr Witold Adamkiewicz Dr Marcin Hołdyński Dr Martin Jonson-Niedziółka Dr Marcin Pisarek. Three basic training courses were organized in June (21 June, 26 June, 27 June and 28 June). In total, ten participants took part in these courses. WP 6.2b. Supporting the analytical lab through the purchase of a rotating disk electrode Completed WP 6.3. Creating an open-access Electronic Laboratory Equipment Database of research equipment available in specialized laboratories in Poland (ELAD) In progress WP 6.5. Industrial/intellectual property right in the IPC PAS 1. 25 patent procedures were supported during the reporting period. Identification numbers assigned for these applications are listed in the table below: No Territory Application Number 1 Poland P-403766 2 Poland P-403789 3 The Netherlands NL 2010852 4 Poland P-404175 5 Poland P-404242 6 Poland P-404256

7 Poland P-404257 8 Poland P-392222 9 Poland P-392364 10 Poland P-392461 11 Switzerland CH 01957/10 12 Poland P-393311 13 Switzerland CH 00234/11 14 Poland P-394698 15 Switzerland CH 00790/11 16 Switzerland CH 01389/11 17 Switzerland CH 01477/11 18 Switzerland CH 01515/11 19 Switzerland CH 01560/11 20 Switzerland CH 00551/12 21 Switzerland CH 00834/12 22 Switzerland CH 00841/12 23 Poland P-401742 24 Switzerland CH 02487/12 25 Germany DE 10 2013 100 494.6 2. During second quarter of 2013, there were 7 patent applications registered for IPC PAS. The numbers given for those applications are as follows: P-403766, P-403789, NL 2010852, P-404175, P- 404242, P-404256, P-404257. Details are summarized in the following tables

Application No Filing Date Title PL Title ENG/GER Inventors P-403766 06.05.2013 P-403789 07.05.2013 Nowy bis(2,2 -bitienylo)-(4- hydroksyfenylo)metanowy ester biotyny, sposób jego wytwarzania, oraz zawierająca ten ester warstwa rozpoznającego polimeru i jej zastosowanie do wykrywania i/lub oznaczania oligonukleotydów Pochodna [C60]fulerenu i sposób jej wytwarzania, warstwa molekularnie wdrukowanego polimeru fulerenowego i sposób jej wytwarzania oraz ich zastosowanie do selektywnego wykrywania i oznaczania adenozyno-5'-trifosforanu (ATP) A new bis(2,2 -bithien-5-yl)-(4- hydroxyphenyl)methane biotin ester, method of its preparation as well as the containing this ester recognition polymer film and its application for detection and/or determination of oligonucleotides [C60]Fullerene derivative and the method of its preparation, molecularly imprinted fullerene polymer film ant the method of its preparation as well as their application for selective detection and determination of adenozine-5'-triphosphate (ATP) Marta Sosnowska, Piotr Pięta, Piyush S. Sharma, Chandra Bikram K.C., Bandi Venugopal, Francis D'Souza, Włodzimierz Kutner Piyush S. Sharma, Marcin Dąbrowski, Krzysztof Noworyta, Chandra Bikram K.C., Tan-Phat Huynh, Janusz Sobczak, Francis D'Souza, Włodzimierz Kutner NL 2010852 24.05.2013 Układ optyczny biegu wiązek laserowych w streczerze w geometrii Öffnera Optical system for directing laser beams in Offner geometry stretcher Yuriy Stepanenko, Tomasz Pietruszka, Michał Nejbauer, Paweł Wnuk, Czesław Radzewicz, Piotr Skibiński, Michał Laskownicki

Application No Filing Date Title PL Title ENG/GER Inventors P-404175 03.06.2013 Nowa pochodna bis(2,2'-bitienylo)metanu i sposób jej wytwarzania, warstwa molekularnie wdrukowanego polimeru, sposób jej wytwarzania i jej zastosowanie do selektywnego wykrywania i oznaczania związków nitroaromatycznych New bis(2,2 -bithienyl)methane derivative and the method of its preparation, film of the molecularly imprinted polymer, method of its preparation, and its application for selective detection and determination of nitroaromatic compounds Tan-Phat Huynh, Marta Sosnowska, Janusz Sobczak, Chandra Bikram K.C., Vladimir N. Nesterov, Francis D'Souza, Włodzimierz Kutner P-404242 07.06.2013 Katalizator Pd/C, sposób otrzymywania katalizatora Pd/C, jego zastosowanie w reakcji elektroredukcji tlenu w ogniwach paliwowych na kwas mrówkowy oraz takie ogniwo paliwowe Pd/C catalyst, preparation method of the Pd/C catalyst, its application in the reaction of oxygen electroreduction in the formic acid fuel cell and such fuel cell Anna Mikołajczuk-Zychora, Andrzej Borodziński, Piotr Kędzierzawski, Leszek Stobiński, Marta Mazurkiewicz, Artur Małolepszy, Agata Kierzek, Karol Juchniewicz P-404256 10.06.2013 Sposób otrzymywania monowarstwy zbudowanej z gęsto upakowanej warstwy nanocząstek pokrytych ligandami hydrofilowymi i hydrofobowymi, monowarstwa i zastosowanie monowarstwy do pokrywania powierzchni Method of obtaining a monolayer composed of closely packed nanoparticles coated with hydrophilic and hydrophobic ligands, monolayer and application of this monolayer to cover surfaces Volodymyr Sashuk, Katarzyna Winkler, Marcin Fiałkowski, Robert Hołyst P-404257 10.06.2013 Sposób modyfikowania powierzchni nanokompozytami, materiał nanokompozytowy i jego zastosowanie Method of modification of surface with Katarzyna Wybrańska, Jan Paczesny, nanocomposites, nanocomposite material and its Marcin Fiałkowski, Robert Hołyst application