Safety data sheet Carbon dioxide, solid (Dry ice).

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1 Revision date : page 1 / 5 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name EC No (from EINECS): CAS No: Index-Nr. - Chemical formula CO2 REACH Registration number: Listed in Annex IV/V of Regulation (EC) No 1907/2006 (REACH), exempted from registration Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial and professional. Perform risk assessment prior to use., Consumer use Details of the supplier of the safety data sheet Company identification Linde Gaz Polska Spolka z o.o., al. Jana Pawla II 41a, Krakow, Poland Address reach@pl.linde-gas.com 1.4. Emergency telephone number Emergency phone numbers (24h): (24 h), (24 h) Poison center Instytut Medycyny Pracy w Lodzi SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification acc. to Regulation (EC) No 1272/2008/EC (CLP/GHS) Classification acc. to Directive 67/548/EEC & 1999/45/EC Not classified as hazardous to health. Asphyxiant in high concentrations Label elements - Hazard Statements EIGA-As - Precautionary Statements Precautionary Statement Prevention Precautionary Statement Response Asphyxiant in high concentrations. Precautionary Statement Storage P403 Store in a well-ventilated place. Precautionary Statement Disposal 2.3. Other hazards Refrigerated solidified gas, exists at -78,5 C. Co ntact with product may cause severe cold burns or frostbite. SECTION 3: Composition/information on ingredients Substance / Mixture: Substance Substances CAS No: Index-Nr.: - EC No (from EINECS): REACH Registration number: Listed in Annex IV/V of Regulation (EC) No 1907/2006 (REACH), exempted from registration. Contains no other components or impurities which will influence the classification of the product Mixtures SECTION 4: First aid measures 4.1. Description of first aid measures First Aid General Information: Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped. First Aid Inhalation: Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped. First Aid Skin / Eye: In case of frostbite spray with water for at least 15 minutes. Apply a sterile dressing. Obtain medical assistance. Immediately flush eyes thoroughly with water for at least 15 minutes. First Aid Ingestion: Swallowing must be absolutely avoided, since coldness and developing pressure could be dangerous. Obtain medical assistance Most important symptoms and effects, both acute and delayed In high concentrations may cause asphyxiation. Symptoms may include loss of mobility/consciousness. Victim may not be aware of asphyxiation. Low concentrations of CO2 cause increased respiration and headache Indication of any immediate medical attention and special treatment needed SECTION 5: Fire fighting measures 5.1. Extinguishing media Suitable extinguishing media All known extinguishants can be used Special hazards arising from the substance or mixture Specific hazards Exposure to fire may cause containers to rupture/explode.

2 Revision date : page 2 / 5 Hazardous combustion products 5.3. Advice for fire-fighters Specific methods Special protective equipment for fire-fighters Normal firefighters equipment consists of an appropriate SCBA (open-circuit positive pressure compressed air type) in combination with fire kit. Equipment and clothing to the following standards will provide a suitable level of protection for firefighters. Guideline: EN 469:2005: Protective clothing for firefighters. Performance requirements for protective clothing for firefighting., EN 137 Respiratory protective devices Self-contained open-circuit compressed air breathing apparatus with full face mask Requirements, testing, marking., EN Footwear for firefighters., EN 443 Helmets for fire fighting in buildings and other structures., EN 659 Protective gloves for firefighters. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Wear self-contained breathing apparatus when entering area unless atmosphere is proved to be safe. Ensure adequate air ventilation. Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous. Use protective clothing Environmental precautions Try to stop release. Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous Methods and material for containment and cleaning up Ventilate area Reference to other sections See also sections 8 and 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Ensure adequate air ventilation. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Contact your gas supplier if in doubt. Refer to supplier's handling instructions. The substance must be handled in accordance with good industrial hygiene and safety procedures. Do not smoke while handling product. Do not remove or deface labels provided by the supplier for the identification of the container contents Conditions for safe storage, including any incompatibilities Keep container in well ventilated place. Observe all regulations and local requirements regarding storage of containers. Keep away from combustible materials. Containers should not be stored in conditions likely to encourage corrosion. Stored containers should be periodically checked for general conditions and leakage. Store containers in location free from fire risk and away from sources of heat and ignition Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure limit value Value type value Note NDS mg/m3 NDSCh mg/m3 TLV (ACGIH) ppm Exposure controls Appropriate engineering controls A risk assessment should be conducted and documented in each work area to assess the risks related to the use of the product and to select the PPE that matches the relevant risk. The following recommendations should be considered. Gas detectors should be used when toxic quantities may be released. Keep concentrations well below occupational exposure limits. Oxygen detectors should be used when asphyxiating gases may be released. The substance must be handled in accordance with good industrial hygiene and safety procedures. Consider work permit system e.g. for maintenance activities. Provide adequate general or local ventilation. Personal protective equipment Eye and face protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mist, gases or dust. Guideline: EN 166 Personal Eye Protection Skin protection Hand protection Advice: Wear cold insulating gloves. Guideline: EN 511 Protective gloves against cold. Other protection Protect eyes, face and skin from contact with product. Respiratory protection Not required Thermal hazards Protect eyes, face and skin from contact with product. Environmental Exposure Controls Specific risk management measures are not required beyond good industrial hygiene and safety procedures. Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for specific methods for waste gas treatment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General information Appearance/Colour: White solid. Odour: No odour warning properties. Melting point: -56,6 C Boiling point: -78,5 C Flash point: Not applicable for gases and gas mixtures. Flammability range: Non flammable. Vapour Pressure 20 C: 57,3 bar Relative density, gas (Air=1): 1,52 Solubility in water: 2000 mg/l Partition coefficient: n-octanol/water: 0,83 logpow

3 Revision date : page 3 / 5 Autoignition temperature: Explosive properties: Explosive acc. EU legislation: Not explosive. Explosive acc. transp. reg.: Not explosive. Oxidising properties: Molecular weight: 44 g/mol Sublimation point: -78,5 C Critical temperature: 31 C Relative density, liquid (Water=1): 1, Other information Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or below ground level. SECTION 10: Stability and reactivity Reactivity Unreactive under normal conditions Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Incompatible materials For material compatibility see latest version of ISO Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects General In high concentrations may cause rapid circulatory insufficiency even at normal levels of oxygen concentration. Symptoms are headache, nausea and vomiting, which may lead to unconsciousness and even death. SECTION 12: Ecological information Toxicity When discharged in large quantities may contribute to the greenhouse effect Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Not classified as PBT or vpvb Other adverse effects Can cause frost damage to vegetation. Global Warming Potential GWP 1 SECTION 13: Disposal considerations Waste treatment methods Do not discharge into any place where its accumulation could be dangerous. Vent to atmosphere in a well ventilated place. Discharge to atmosphere in large quantities should be avoided. Contact supplier if guidance is required. Refer to the EIGA code of practice (Doc.30 Disposal of Gases", downloadable at for more guidance on suitable disposal methods. SECTION 14: Transport information ADR/RID IMDG Labels: 9 EmS: F-C, S-V P003

4 Revision date : page 4 / Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code IATA Labels: 9 P954 Other transport information Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Ensure adequate ventilation. This transport is not submitted to ADR/RID. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Seveso Directive 96/82/EC: Not covered. Other regulations Rozporzadzenie nr 1907/2006 Parlamentu Europejskiego i Rady z dnia 18 grudnia 2006 r. w sprawie rejestracji, oceny, udzielania zezwolen i stosowanych ograniczen w zakresie chemikaliów (REACH), utworzenia Europejskiej Agencji Chemikaliów, zmieniajace dyrektywe 1999/45/WE oraz uchylajace rozporzadzenie Rady (EWG) nr 793/93 i rozporzadzenie Komisji (WE) nr 1488/94, jak rowniez dyrektywe Rady 76/769/EWG i dyrektywy Komisji 91/155/EWG, 93/67/EWG, 93/105/WE i 2000/21/WE (Dz.U. L 396/1 z ), wraz z pozniejszymi zmianami. Rozporzadzenie Komisji (UE) NR 453/2010 z dnia 20 maja 2010 r. zmieniajace rozporzadzenie (WE) nr 1907/2006 Parlamentu Europejskiego i Rady w sprawie rejestracji, oceny, udzielania zezwolen i stosowanych ograniczen w zakresie chemikaliow (REACH) (Dz.U. L 133/1 z ). Rozporzadzenie Parlamentu Europejskiego i Rady (WE) nr 1272/2008 z dnia 16 grudnia 2008 r. w sprawie klasyfikacji, oznakowania i pakowania substancji i mieszanin, zmieniajace i uchylajace dyrektywy 67/548/EWG i 1999/45/WE oraz zmieniajace rozporzadzenie (WE) nr 1907/2006 (Dz.U. L 353/2 z ). Rozporzadzenie Komisji (WE) nr 790/2009 z dnia 10 sierpnia 2009 r. dostosowujace do postepu naukowo-technicznego rozporzadzenie Parlamentu Europejskiego i Rady (WE) nr 1272/2008 z dnia 16 grudnia 2008 r. w sprawie klasyfikacji, oznakowania i pakowania substancji i mieszanin (Dz.U. L 235/1 z ). Rozporzadzenie Komisji (UE) nr 286/2011 z dnia 10 marca 2011 r. dostosowujace do postepu naukowo-technicznego rozporzadzenie Parlamentu Europejskiego i Rady (WE) nr 1272/2008 w sprawie klasyfikacji, oznakowania i pakowania substancji i mieszanin(dz. U. L 83/1 z ). Dyrektywa Parlamentu Europejskiego i Rady 2008/112/WE z dnia 16 grudnia 2008 r. zmieniajaca dyrektywy Rady 76/768/EWG, 88/378/EWG, 1999/13/WE oraz dyrektywy 2000/53/WE, 2002/96/WE i 2004/42/WE Parlamentu Europejskiego i Rady w celu dostosowania ich do rozporzadzenia (WE) nr 1272/2008 w sprawie klasyfikacji, oznakowania i pakowania substancji i mieszanin (Dz.Urz. UE L 345/68 z ). Rozporzadzenie Parlamentu Europejskiego i Rady (WE) nr 1336/2008 z dnia 16 grudnia 2008 r. zmieniajace rozporzadzenie (WE) nr 648/2004 w celu dostosowania go do rozporzadzenia (WE) nr 1272/2008 w sprawie klasyfikacji, oznakowania i pakowania substancji i mieszanin.(dz.urz. UE L 354/60 z ). Ustawa z dnia 25 lutego 2011 o substancjach chemicznych i ich mieszaninach (Dz. U. z 2011 r. Nr 63, poz. 322). Rozporzadzenie Ministra Zdrowia z dnia 10 sierpnia 2012 r. w sprawie kryteriow i sposobu klasyfikacji substancji chemicznych i ich mieszanin (Dz. U r. poz. 1018). Rozporzadzenie Ministra Zdrowia z dnia 20 kwietnia 2012 r. w sprawie oznakowania opakowan substancji niebezpiecznych i mieszanin niebezpiecznych oraz niektorych mieszanin (Dz. U. 2012r. poz. 445). Rozporzadzenie Ministra Zdrowia z dnia 24 lipca 2012 r. w sprawie substancji chemicznych, ich mieszanin, czynnikow lub procesow

5 Revision date : page 5 / 5 technologicznych o dzialaniu rakotworczym lub mutagennym w srodowisku pracy (Dz. U r. poz. 890). Rozporzadzenie Ministra Zdrowia z dnia 30 grudnia 2004 r. w sprawie bezpieczenstwa i higieny pracy zwiazanej z wystepowaniem w miejscu pracy czynnikow chemicznych (Dz. U. z 2005 r. Nr 11, poz. 86), wraz z pozniejszymi zmianami. Rozporzadzenie Ministra Pracy i Polityki Spolecznej z dnia 29 listopada 2002 r. w sprawie najwyzszych dopuszczalnych stezen i natezen czynnikow szkodliwych dla zdrowia w srodowisku pracy (Dz. U. z 2002 r. Nr 217, poz. 1833), wraz z pozniejszymi zmianami. Ustawa z dnia 14 grudnia 2012 o odpadach (Dz. U. z 2013 r. poz. 21). Rozporzadzenie Ministra Srodowiska z dnia 27 wrzesnia 2001 r. w sprawie katalogu odpadow. (Dz. U. z 2001 r. Nr 112, poz. 1206). Rozporzadzenie Ministra Gospodarki, Pracy i Polityki Spolecznej z dnia 23 grudnia 2003 r. w sprawie bezpieczenstwa i higieny pracy przy produkcji i magazynowaniu gazów, napelnianiu zbiorników gazami oraz uzywaniu i magazynowaniu karbidu (Dz. U. z 2004 r. Nr 7, poz. 59). Council Directive 89/391/EEC on the introduction of measures to encourage improvements in the safety and health of workers at work Directive 89/686/EEC on personal protective equipment Council Directive 67/548/EEC on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances Directive 1999/45/EC concerning the approximation of the laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations Directive 97/23/EC on the approximation of the laws of the Member States concerning pressure equipment. This Safety Data Sheet has been produced to comply with Regulation (EU) 453/2010. Agency for Toxic Substances and Diseases Registry (ATSDR) ( European Chemical Agency: Guidance on the Compilation of Safety Data Sheets. European Chemical Agency: Information on Registered Substances European Industrial Gases Association (EIGA) Doc. 169/11 Classification and Labelling guide. ISO 10156:2010 Gases and gas mixtures -- Determination of fire potential and oxidizing ability for the selection of cylinder valve outlets. International Programme on Chemical Safety ( Matheson Gas Data Book, 7th Edition. National Institute for Standards and Technology (NIST) Standard Reference Database Number 69 The ESIS (European chemical Substances 5 Information System) platform of the former European Chemicals Bureau (ECB) ESIS ( The European Chemical Industry Council (CEFIC) ERICards. Threshold Limit Values (TLV) from the American Conference of Governmental Industrial Hygienists (ACGIH). United States of America s National Library of Medicine s toxicology data network TOXNET ( Substance specific information from suppliers. Linde safety advice No. 3 Oxygen deficiency End of document Chemical safety assessment A CSA does not need to be carried out for this product. SECTION 16: Other information Ensure all national/local regulations are observed. The hazard of asphyxiation is often overlooked and must be stressed during operator training. Before using this product in any new process or experiment, a thorough material compatibility and safety study should be carried out. Advice Whilst proper care has been taken in the preparation of this document, no liability for injury or damage resulting from its use can be accepted. Details given in this document are believed to be correct at the time of going to press. Further information Please note that there has been a change in the system that has been used to create this SDS, therefore its number and revision may not correspond to versions that have previously been distributed. References Various sources of data have been used in the compilation of this SDS, they include but are not exclusive to: